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You can 100% mix metals in your loop, copper and aluminum included if and only if you use a corrosion inhibitor. Copper and aluminum mix too well, and you'll get a nasty surprise in your liquid if you mix these two common metals in your loop without corrosion inhibition.
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I'm not so sure that a corrosion inhibitor will prevent
electrolysis. I personally would err on the side of caution and try not to mix the metals used in your loop.