What does the LCD poster say? Also you can try to wiggle the BIOS chip. For some reason I had the same problem with a 680i board (EVGA though, not Asus) that it would not post every couple of months unless I wiggled the BIOS chip, that board had LED diagnostic readout would even read 'FF' which meant it was booted proper. As someone else above said, I would pull it from the case, you may be shorting it on something which would definitely cause the problem.
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