There is no telling what your temps will be like with water. There are too many variables. CPU block, GPU blocks, pumps, radiator configurations, room temperature, stress level on cpu/gpu's.
If your rig is already quiet and runs fairly cool then why go water? Just feeling the need to tinker and got a bit of an upgrade itch?
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"Water cooling is basically like injecting drugs into your veins and you'll find that what once was enough is quickly not enough anymore."
-Linus
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